The gpx file has times in UTC timecodes (that's the gpx standard). You can see the correct coordinates in the gpx file are between these two points:
<trkpt lat="43.318241" lon="11.329464"><ele>335.310364</ele><time>2025-09-23T09:17:22Z</time></trkpt> <trkpt lat="43.318241" lon="11.329464"><ele>335.310364</ele><time>2025-09-23T09:22:23Z</time></trkpt>
On google maps that is these coordinates: https://www.google.com/maps/place/43%C2%B019'05.7%22N+11%C2%B019'46.1%22E/@43.318241,11.3268891,1125m/data=!3m2!1e3!4b1!4m4!3m3!8m2!3d43.318241!4d11.329464?entry=ttu&g_ep=EgoyMDI1MTAwMS4wIKXMDSoASAFQAw%3D%3D
On the piazza San Giovanni right next to the Duomo Di Sienna.
The Raw file indicates it was taken on 2025-09-23T09:20:23.11 in the local timezone. You can see that that appears to be correct with the two points above, however the gpx file uses the UTC description (that's what the Z at the end of the timecodes means) so that actually makes the time 2 hours off in the file! Italy in summer is two hours difference from the UTC standard (UTC is basically GMT).
Was it 9:20 am local time when you took that picture? If so the coding in the gpx file is wrong indeed. If it was actually 11:20am when you shot the picture the time coding in the gpx file is correct.
I discovered where the 6 hours come from. That is the timezone on my computer which is in the UTC/GMT-6:00 timezone. So the offset for you is going to be different. The problem is that Lightroom assumes that when you import an image, it was taken in the timezone your computer is set to. So with the (apparently wrong timezone coding in the gpx file and the fact that I am in the USA Denver region, that results in a 6 hour offset. For you in Britain, it should be a 1 hour offset that you need to dial in.
So I think there are one and maybe two issues. One, the assumption that Lightroom makes that imported images are taken in the timezone set in your computer and two: the gpx might be incorrectly time coded (depending on what local time you actually shot the image).
The lightroom issue is unfortunately a long standing issue with timezone support in Lightroom. It is caused by the absence of any standard to record timezones in camera but terribly annoying for sure and the assumption that Lightroom makes is not necessarily bad in general but is terrible for anybody (like us both apparently) that travels a lot. Daylight savings time (or summer/winter time) complicates that even further. I constantly have to correct for timezones, summer/winter time and more as cameras are just not smart enough to deal with this correctly. They really should be recording time in the raw files in UTC format but no camera that I have does that. They all just put the time in in whatever you set in the clock. So had you imported the images while still in Italy, everything would be working fine (apart from the two hour error in the gpx file), but since you imported while in Britain, you got the timecode offset.
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